Given The Following Reaction: CuO (s) + H2 (g) Cu (s) + H2O (g) If 250. L Of Hydrogen Gas Are Used To analyze the chemical process, it is essential to understand the fundamentals of the reaction, the stoichiometry involved, and the practical applications of this chemical transformation. This reaction exemplifies a reduction process where copper(II) oxide (CuO) reacts with hydrogen gas (H2) to produce metallic copper (Cu) and water vapor (H2O). In this article, we will delve into the details of this reaction, explore the calculations involved in quantifying reactants and products, and discuss its significance in industrial and laboratory settings.
Understanding the Reaction: CuO and Hydrogen Gas
Reaction Overview
This chemical reaction is a classic example of a reduction-oxidation (redox) process. Copper(II) oxide (CuO) acts as an oxidizing agent, accepting electrons from hydrogen gas, which serves as the reducing agent. The overall reaction can be written as:CuO (s) + H2 (g) → Cu (s) + H2O (g)
In this process, solid copper metal is produced alongside water vapor, which may be in gaseous form depending on temperature and pressure conditions.
Significance of the Reaction
This reaction is vital in several contexts:- Metallurgical processes: Extracting pure copper from its oxide ore.
- Laboratory synthesis: Demonstrating redox reactions and stoichiometry.
- Industrial applications: Producing copper metal and water vapor in controlled environments.
Calculating the Moles of Hydrogen Gas Used
Given Volume and Conditions
The problem states that 250 liters of hydrogen gas are used. To perform calculations accurately, assumptions about temperature and pressure are necessary, typically assuming standard temperature and pressure (STP), where:- Temperature = 273.15 K
- Pressure = 1 atm
- 1 mol of gas occupies 22.4 liters at STP
Converting Volume to Moles
Using the molar volume at STP:Number of moles of H2 = Volume of H2 / Molar volume
= 250 L / 22.4 L/mol
≈ 11.16 mol
This means approximately 11.16 moles of hydrogen gas are involved in the reaction.
Stoichiometry of the Reaction
Balanced Chemical Equation
The reaction is already balanced:CuO (s) + H2 (g) → Cu (s) + H2O (g)
This indicates a 1:1 molar ratio between CuO and H2, and between H2 and H2O.
Reactant and Product Quantities
- For every 1 mol of H2 consumed, 1 mol of CuO reacts.
- The amount of water produced correlates directly with hydrogen consumption.
Mass and Volume Calculations
Mass of Copper Produced
Using molar mass:- Molar mass of Cu = 63.55 g/mol
This indicates that approximately 709.8 grams of metallic copper can be produced from 250 L of hydrogen gas under the specified conditions.
Volume of Water Vapor Produced
Since water is produced as a gas (H2O vapor), and assuming ideal gas behavior at STP:Volume of H2O vapor = moles of H2O × molar volume
= 11.16 mol × 22.4 L/mol
≈ 250 L
Thus, the reaction produces approximately 250 liters of water vapor, matching the volume of hydrogen used, assuming all hydrogen is consumed.
Practical Applications and Industrial Relevance
Metallurgical Extraction of Copper
This reaction is fundamental in the smelting and refining of copper ores. Copper oxides are reduced to metallic copper using hydrogen, which is a cleaner alternative to carbon reduction methods, reducing sulfur dioxide emissions.Hydrogen as a Reducing Agent
Hydrogen gas offers several advantages:- Produces water instead of greenhouse gases like CO2.
- Enables pure copper recovery.
- Suitable for environmentally friendly metal extraction processes.
Laboratory and Educational Uses
This reaction serves as an excellent demonstration of redox chemistry, stoichiometry, and gas-volume relationships at STP.Additional Considerations
Reaction Conditions
- Temperature: Elevated temperatures favor the reduction process.
- Pressure: Increased pressure can influence gas volumes and reaction rates.
- Purity of reactants: Impurities can affect reaction efficiency.
Limitations and Safety
- Hydrogen gas is flammable and requires careful handling.
- Proper ventilation and safety protocols are necessary during experiments or industrial operations.
Summary and Conclusion
Analyzing the reaction between copper(II) oxide and hydrogen gas reveals how stoichiometry and gas laws interplay to determine reactant and product quantities. Using 250 liters of hydrogen gas at STP corresponds to roughly 11.16 moles, which theoretically produces about 709.8 grams of copper and 250 liters of water vapor. This process exemplifies efficient reduction techniques crucial in metal extraction industries, highlighting the importance of chemical calculations in practical applications.In conclusion, understanding the quantitative aspects of this redox reaction enables chemists and engineers to optimize processes, predict yields, and design environmentally friendly methods for metal recovery. The reaction's simplicity, combined with its industrial significance, underscores the central role of stoichiometry and gas laws in modern chemistry.